Statistical comparison of proposed method with reference methods.
| Samples | F – test resultsa | ||||
|---|---|---|---|---|---|
| (s12/s22)15 | (s12/s32)26 | (s12/s42)31 | (s12/s52)33 | (s12/s62)28 | |
| Water | 0.127 | 0.58 | 0.23 | 0.0019 | |
| Water | 0.0516 | 0.063 | 0.028 | 0.37 | |
| Water | 0.219 | 0.100 | 0.273 | ||
| Water | 0.119 | ||||
| Blood | 0.95 | ||||
| Blood | 0.52 | ||||
| Blood | 0.73 | ||||
| Soil | 0.32 | 0.0002 | 0.0004 | ||
| Soil | 0.95 | 0.0003 | 0.0007 | ||
| Soil | 1.0 | 0.0001 | 0.0001 | ||
| Alloy | 0.074 | ||||
| Alloy | 0.12 | ||||
| Synthetic mixture | 0.13 | ||||
| Synthetic mixture | 0.52 | ||||
| Synthetic mixture | 0.72 | ||||
| Food | 0.79 | ||||
| Food | 0.68 | ||||
| Urine | 1.02 | ||||
| Urine | 0.84 | ||||
| Tea | 0.98 | ||||
| Wheat | 0.76 | ||||
Tabulated F-value for (5, 5) degrees of freedom at P(0.98) is 5.72. s1 = standard deviation of proposed method, s2 = standard deviation of reference method,15s3 = standard deviation of reference method,26s4 = standard deviation of reference method,31s5 = standard deviation of reference method,33s6 = standard deviation of reference method.28