Scope of aryl nitro reduction reactions with the AgNPs/textile catalysta.
Entry | Substrate | Product | Time | Yieldb |
---|---|---|---|---|
1 | 3 hours | 73.4% | ||
2 | 7 hours | 54% | ||
3c | 7 hours | 81% | ||
4 | 4 hours | 70% | ||
5 | 10 hours | 91.2% | ||
6 | 3 hours | 55.6% | ||
7 | 12 hours | 33.5% | ||
8 | 12 hours | 58.3% | ||
9 | 7 hours | 72.5% |
Reaction conditions: 0.2 mmol substrate, 1 mmol NaBH4 and 2 cm2 TsNS catalyst were mixed in THF/H2O (1 mL/1 mL) in a 20 mL glass vial at room temperature.
Isolated yield.
Reaction carried out at 100 °C.