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. 2018 Feb 7;8(12):6288–6292. doi: 10.1039/c7ra13257c

Scope of aryl nitro reduction reactions with the AgNPs/textile catalysta.

Entry Substrate Product Time Yieldb
1 graphic file with name c7ra13257c-u1.jpg graphic file with name c7ra13257c-u2.jpg 3 hours 73.4%
2 graphic file with name c7ra13257c-u3.jpg graphic file with name c7ra13257c-u4.jpg 7 hours 54%
3c graphic file with name c7ra13257c-u5.jpg graphic file with name c7ra13257c-u6.jpg 7 hours 81%
4 graphic file with name c7ra13257c-u7.jpg graphic file with name c7ra13257c-u8.jpg 4 hours 70%
5 graphic file with name c7ra13257c-u9.jpg graphic file with name c7ra13257c-u10.jpg 10 hours 91.2%
6 graphic file with name c7ra13257c-u11.jpg graphic file with name c7ra13257c-u12.jpg 3 hours 55.6%
7 graphic file with name c7ra13257c-u13.jpg graphic file with name c7ra13257c-u14.jpg 12 hours 33.5%
8 graphic file with name c7ra13257c-u15.jpg graphic file with name c7ra13257c-u16.jpg 12 hours 58.3%
9 graphic file with name c7ra13257c-u17.jpg graphic file with name c7ra13257c-u18.jpg 7 hours 72.5%
a

Reaction conditions: 0.2 mmol substrate, 1 mmol NaBH4 and 2 cm2 TsNS catalyst were mixed in THF/H2O (1 mL/1 mL) in a 20 mL glass vial at room temperature.

b

Isolated yield.

c

Reaction carried out at 100 °C.