The determination and recovery of Co(ii) in green leaf vegetable samples by the proposed method and FAAS (n = 3).
Sample | Spiked (mg g−1) | VALS-DLLME | FAAS | ||||
---|---|---|---|---|---|---|---|
Found (mg g−1) | Recovery (%) | RSD (%) | Found (mg g−1) | Recovery (%) | RSD (%) | ||
Mint | 0.00 | NDa | — | — | ND | — | — |
0.25 | 0.246 | 98.4 | 0.78 | 0.249 | 99.7 | 1.21 | |
0.50 | 0.495 | 99.0 | 1.67 | 0.496 | 99.2 | 2.65 | |
1.50 | 1.507 | 100.5 | 1.87 | 1.512 | 100.8 | 2.13 | |
Spinach | 0.00 | ND | — | — | ND | — | — |
0.25 | 0.226 | 90.2 | 0.98 | 0.228 | 91.3 | 0.59 | |
0.50 | 0.491 | 98.2 | 2.13 | 0.507 | 101.3 | 1.24 | |
1.50 | 1.503 | 100.2 | 2.43 | 1.521 | 101.4 | 2.57 | |
Kale | 0.00 | ND | — | — | ND | — | — |
0.25 | 0.236 | 94.2 | 2.53 | 0.248 | 99.1 | 0.76 | |
0.50 | 0.489 | 97.9 | 2.36 | 0.491 | 98.1 | 1.43 | |
1.50 | 1.554 | 103.6 | 1.89 | 1.523 | 101.5 | 0.98 | |
Cabbage | 0.00 | ND | — | — | ND | — | — |
0.25 | 0.242 | 96.8 | 1.09 | 0.246 | 98.4 | 1.32 | |
0.50 | 0.496 | 99.1 | 2.34 | 0.506 | 101.2 | 2.36 | |
1.50 | 1.456 | 97.1 | 1.54 | 1.556 | 103.7 | 2.41 | |
Chinese cabbage | 0.00 | ND | — | — | ND | — | — |
0.25 | 0.241 | 96.4 | 1.24 | 0.244 | 97.6 | 0.97 | |
0.50 | 0.493 | 98.6 | 2.32 | 0.503 | 100.6 | 1.23 | |
1.50 | 1.498 | 99.9 | 1.14 | 1.515 | 101.1 | 1.09 |
ND: not detected.