The determination and recovery of Co(ii) in vitamin B12 samples by the proposed method and FAAS (n = 3).
Sample | Spiked (mg g−1) | VALS-DLLME | FAAS | ||||
---|---|---|---|---|---|---|---|
Found (mg g−1) | Recovery (%) | RSD (%) | Found (mg g−1) | Recovery (%) | RSD (%) | ||
No. I (1 tablet = 0.1509 g) | 0.000 | 0.729 | — | — | 0.762 | — | — |
0.165 | 0.868 | 94.1 | 1.24 | 0.888 | 94.0 | 2.49 | |
0.331 | 1.054 | 99.6 | 2.43 | 1.067 | 101.8 | 1.57 | |
0.994 | 1.736 | 101.1 | 1.09 | 1.749 | 102.3 | 0.98 | |
No. II (1 tablet = 0.1374 g) | 0.000 | 0.699 | — | — | 0.706 | — | — |
0.182 | 0.859 | 86.0 | 1.54 | 0.888 | 99.0 | 1.26 | |
0.364 | 1.077 | 102.7 | 0.98 | 1.084 | 103.0 | 2.37 | |
1.092 | 1.776 | 99.7 | 2.32 | 1.849 | 104.3 | 1.57 | |
No. III (1 tablet = 0.1270 g) | 0.000 | 0.701 | — | — | 0.702 | — | — |
0.197 | 0.882 | 92.0 | 1.43 | 0.898 | 98.0 | 1.43 | |
0.394 | 1.087 | 99.5 | 1.57 | 1.118 | 104.5 | 1.89 | |
1.181 | 1.882 | 100.7 | 0.69 | 1.953 | 105.7 | 0.94 | |
No. IV (1 tablet = 0.3056 g) | 0.000 | 0.111 | — | — | 0.115 | — | — |
0.081 | 0.187 | 92.0 | 2.12 | 0.193 | 93.1 | 2.31 | |
0.164 | 0.272 | 97.0 | 3.45 | 0.275 | 99.0 | 1.54 | |
0.491 | 0.605 | 100.7 | 1.34 | 0.612 | 101.0 | 0.92 | |
No. V (1 tablet = 0.3924 g) | 0.000 | 0.036 | — | — | 0.038 | — | — |
0.064 | 0.097 | 96.0 | 1.57 | 0.092 | 84.0 | 1.27 | |
0.127 | 0.163 | 98.5 | 2.58 | 0.168 | 102.4 | 0.93 | |
0.382 | 0.415 | 99.3 | 2.63 | 0.426 | 101.3 | 1.38 |