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. 2018 Feb 20;8(15):8118–8129. doi: 10.1039/c7ra13423a

Thermodynamic properties of Dy for Cu–Dy intermetallic compounds in two-phase coexisting states at different temperatures.

T/K E eq/V vs. Ag/AgCl ΔE/V vs. Dy(iii)/Dy ΔDy/kJ (mol Dy)−1 a Dy
Plateau(Dy)
773 −1.943 ± 0.003
803 −1.925 ± 0.005
833 −1.917 ± 0.002
863 −1.912 ± 0.002
Plateau D In the two-phase coexisting state between Cu5Dy and Cu
773 −1.557 ± 0.001 0.386 ± 0.004 −111.75 ± 1.16 2.81 × 10−8
803 −1.546 ± 0.004 0.379 ± 0.009 −109.72 ± 2.61 7.29 × 10−8
833 −1.54 ± 0.003 0.377 ± 0.005 −109.14 ± 1.45 1.43 × 10−7
863 −1.538 ± 0.005 0.374 ± 0.007 −108.27 ± 2.03 2.79 × 10−7
Plateau C In the two-phase coexisting state between Cu9/2Dy and Cu5Dy
773 −1.686 ± 0.002 0.257 ± 0.005 −74.40 ± 1.45 9.38 × 10−6
803 −1.678 ± 0.004 0.247 ± 0.009 −71.51 ± 2.61 2.23 × 10−5
833 −1.675 ± 0.002 0.242 ± 0.004 −70.06 ± 1.61 4.04 × 10−5
863 −1.671 ± 0.001 0.241 ± 0.003 −69.77 ± 0.87 5.98 × 10−5
Plateau B In the two-phase coexisting state between Cu2Dy and Cu9/2Dy
773 −1.763 ± 0.004 0.18 ± 0.007 −52.11 ± 2.03 3.01 × 10−4
803 −1.750 ± 0.003 0.175 ± 0.008 −50.66 ± 2.32 5.06 × 10−4
833 −1.746 ± 0.006 0.171 ± 0.008 −49.51 ± 2.32 7.86 × 10−4
863 −1.743 ± 0.004 0.169 ± 0.006 −48.93 ± 1.74 1.09 × 10−3
Plateau A In the two-phase coexisting state between CuDy and Cu2Dy
773 −1.843 ± 0.004 0.1 ± 0.007 −28.95 ± 2.03 1.11 × 10−2
803 −1.828 ± 0.003 0.097 ± 0.008 −28.08 ± 2.32 1.49 × 10−2
833 −1.826 ± 0.004 0.091 ± 0.006 −26.35 ± 1.74 2.23 × 10−2
863 −1.823 ± 0.005 0.089 ± 0.007 −25.77 ± 2.03 2.76 × 10−2