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. 2018 Feb 28;8(17):9057–9062. doi: 10.1039/c7ra11383h

Fluorescence analysis of Cu2+ and hemin: a comparison of the proposed approach with other reported methods.

Probe Mechanism Linear range (μM) LOD (μM) Ref.
Analysis of Cu 2+
BSA-capped AuNCs Electrostatic & ion-exchanging 30–500 0.5 30
BSA-capped AuNCs Coordination & energy transfer 0.5–100 0.3 31
BSA-capped AuNCs Precipitation 5–500 5.0 32
BSA-capped CuNCs Intersystem crossing 0.02–34 0.001 33
DNA-capped Cu/Ag NCs/MPAa Oxidation 0.005–0.2 0.0027 34
PEI-capped AgNCsb Coordination & energy transfer 0.01–7.7 0.01 35
PMAA-capped AgNCsc Coordination & energy transfer 0.01–30 0.01 36
Sn(ii)-citrate-capped AuNCs Coordination 0.5–70 0.38 38
DTT-capped AuNCsd Coordination 0–60 0.08 39
Penicillamine-capped CuNCs Formation-induced FL 14.8–99.2 4.69 40
Cytidine-stabilized CuNCs Formation-induced FL 0.05–2.0 0.032 This work
Analysis of hemin
Curcumin polymer Electron density transfer 20–100 13.5 21
Hep–MPA–CdS QDs/protaminee Static interaction & surface defect 0.167–17 0.0486 22
DNA–rGO/AOf Competition & electron or energy transfer 0.31–2.5 0.05 23
Cytidine-stabilized CuNCs Inner filter effect 0.05–4.0 0.045 This work
a

DNA-capped Cu/Ag nanoclusters in the presence of 3-mercaptopropionic acid.

b

Polyethyleneimine-capped AgNCs.

c

poly(methacrylic acid)-capped AgNCs.

d

Dithiothreitol-capped AuNCs.

e

Heparin–mercaptopropionic acid dual modified CdS quantum dots in the presence of protamine.

f

DNA-reduced graphene oxide in the presence of acridine orange.