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. 2018 Mar 1;8(17):9152–9160. doi: 10.1039/c8ra01316k

Catalytic results of Co/ZrO2 for hydrogenation of EL in different solventsa.

Entry Solvent EL conv. (%) GVL yield (%) Co leachingb (%)
1 Water 97.4 91.8 28.4
2 Methanol 97.3 58.7 0.8
3 Ethanol >99.5 84.9 0.8
4 2-Propanol 63.2 53.1 0.4
5 1-Propanol >99.5 84.9 0.2
6 1-Butanol >99.5 86.7 0.6
7 1-Pentanol 78.7 64.2 0.5
8 Cyclohexane >99.5 80.0 DNT
9 Benzene 1.0 0.8 DNT
10 1,4-Dioxane >99.5 83.5 0.46
a

Reaction conditions: 17.4 mmol EL, 15 mL solvent, 190 °C, 4 MPa H2, 2 h and 0.1 g Co/ZrO2.

b

Determined by ICP.