Catalytic results of Co/ZrO2 for hydrogenation of EL in different solventsa.
Entry | Solvent | EL conv. (%) | GVL yield (%) | Co leachingb (%) |
---|---|---|---|---|
1 | Water | 97.4 | 91.8 | 28.4 |
2 | Methanol | 97.3 | 58.7 | 0.8 |
3 | Ethanol | >99.5 | 84.9 | 0.8 |
4 | 2-Propanol | 63.2 | 53.1 | 0.4 |
5 | 1-Propanol | >99.5 | 84.9 | 0.2 |
6 | 1-Butanol | >99.5 | 86.7 | 0.6 |
7 | 1-Pentanol | 78.7 | 64.2 | 0.5 |
8 | Cyclohexane | >99.5 | 80.0 | DNT |
9 | Benzene | 1.0 | 0.8 | DNT |
10 | 1,4-Dioxane | >99.5 | 83.5 | 0.46 |
Reaction conditions: 17.4 mmol EL, 15 mL solvent, 190 °C, 4 MPa H2, 2 h and 0.1 g Co/ZrO2.
Determined by ICP.