Influence of different catalysts for synthesis of pentafulvenea.
Entry | Catalyst | Yieldb (%) |
---|---|---|
1 | KCC-1 | — |
2 | Fe3O4/KCC-1/APTPOSS | — |
3 | Fe3O4/KCC-1/APTPOSS/salen/Pd(ii) | 92 |
4 | Nano-SiO2/salen/Pd(ii) | 53 |
5 | MCM-41/salen/Pd(ii) | 74 |
6 | SBA-15/salen/Pd(ii) | 80 |
7 | Salen/Pd(ii) | 83 |
Reaction conditions: 2-acetyl-benzaldehyde (10 mmol), cyclopentadiene (70 mmol), and catalyst (6 mg), at room temperature for 3 h.
Isolated yield.