The structural parameters of (−)-1/(+)-1-TCNQ determined via X-ray single crystal diffraction.

Bond length		Bond angle
Pt1–C1	1.989(12)	C1–Pt1–C2	99.7(4)
Pt1–C2	1.912(9)	C1–Pt1–N1	82.9(4)
Pt1–N1	1.917(9)	C1–Pt1–N2	161.4(4)
Pt1–N2	2.100(8)	C2–Pt1–N1	177.2(4)
C36–C39	1.429(17)	C2–Pt1–N2	98.8(4)
C34–C35	1.320(16)	N1–Pt1–N2	78.7(4)
C37–C38	1.319(17)
C33–C42	1.359(18)