Emission data of several meso-porphyrin and a selection of zinc meso-metalloporphyrins.
| Compound | Q(0,0), Q(0,1) (nm) | ϕ f | τ f (ns) | Solvent | Ref. |
|---|---|---|---|---|---|
| meso-Porphyrins | |||||
| H2TPP | 656, 717 | 0.09 | — | CH2Cl2 | 50 |
| H2TEBOP | 657, 720 | 0.035 | 8.0 | CH2Cl2 | Current work |
| meso-Porphyrin zinc( ii ) complexes | |||||
| [Zn(TPP)] | 597, 647 | 0.037 | 1.9 | CH2Cl2 | 50 |
| [Zn(TEBOP)] | 603, 651 | 0.030 | 1.2 | CH2Cl2 | Current work |
| [Zn(TEBOP)(4,4′-bpy)] (3) | 603, 651 | 0.028 | 1.2 | CH2Cl2 | Current work |
| [Zn(TTP)(mbpy∼py)]a | 611, 652 | 0.021 | — | CH2Cl2 | 45 |
| [Zn(TPP)(IQNO)]b | 602, 656 | — | 1.9 | Ethyl acetate | 31 |
| [Zn(TPP)(1,4-dioxane)2] | 604, 655 | — | 1.8 | Dioxane | 17 |
a
mbpy∼py = 4′-Methyl-4-(2-(4-pyridyl)ethenyl)-2,2′-bipyridine.
b
IQNO = isoquinonine N-oxide.