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. 2018 Jun 20;8(40):22710–22728. doi: 10.1039/c8ra03296c

Advantages and disadvantages of incorporating polymer and inorganic additives in the PES membrane matrix.

Membrane synthesis approach Advantages Disadvantages
Blending with a polymer (a) Miscibility in common solvents (a) Tendency toward physical and/or chemical aging
(b) Flexible to incorporate (b) Leaching during the preparation and operation process, which may reduce the efficiency
(c) Poor compatibility in the polymer matrix
Blending with an inorganic material (a) High chemical resistance (a) More expensive than equivalent polymeric ones
(b) Improve thermal stability (b) Defect-free commercial-scale inorganic PES membranes are difficult to manufacture
(c) The resultant membrane combines the advantages of the organic and inorganic parts (c) Stability of the doped form is a big issue due to its nano-size
(d) Can be easily incorporated (d) Very expensive formulations
(e) Provides an enhanced surface that allows multiple functional groups to be added on the membrane surface (e) Non-uniform dispersion of NPs in the polymer matrix
(f) Aggregation phenomenon
(g) Weak interaction with the polymer matrix
(h) Leaching of NPs during the operation process
(i) Uncontrollable pore size
(j) Poor dissolution in various organic solvents