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Fig. 7. First-order plots for the photooxidation of Trp (20 μM) photosensitized by (A) TCP (■) and TCP in presence of d-mannitol (□), (B) TCP-C60 (▲) and TCP-C60 in presence of d-mannitol (△) and (C) TCP-C604+ (▼) and TCP-C604+ in presence of d-mannitol (▽) in DMF/5% water; λirr = 562 nm.