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. 2018 Jun 26;8(41):23130–23151. doi: 10.1039/c8ra03156h

Summary of recent research on gas separation with (r)GO-assisted membranesa.

Membrane materials Synthesis methods Membrane thickness Gas selectivity Gas permeability, barrer Ref.
Pure GO Spin coating 20 nm H2/CO2: ca. 240 H2: 3.4 × 10−7 mol (m2 s−1 Pa) 138
GO/K2B4O7/PES Vacuum filtration CO2/CH4: 75 CO2: 650 GPU 139
GO/PEBA Casting CO2/N2: 80 CO2: 110 barrer 140
ZIF-8/GO Contra-diffusion 100 nm H2/C3H8: 405 H2: 5.46 × 10−8 mol (m2 s−1 Pa) 141
H2/N2: 11.1
UiO-66-NH2/GO Vacuum filtration 1.9 μm H2/N2: 9.75 H2: 3.9 × 10−8 mol (m2 s−1 Pa) 142
H2/CO2: 6.35
(PDMS)/GO Casting and thermal treatment ca. 100 μm CO2/N2: 24 CO2: 27.7 barrer 143
Pebax/ZIF-8/GO Casting and thermal treatment 55–65 μm CO2/N2: 47.6 CO2: 249 barrer 144
Pebax/r-GO Solution-casting 45–60 μm CO2/N2: 104 CO2: 119 barrer 94
Pure GO Spray coating 1 μm H2/CO2: 20.9 H2: 2.7 × 10−8 mol (m2 s−1 Pa) 141
PEI/GO LBL assembly 1 μm H2/CO2: 30 H2: 1000 barrer 93
a

1 GPU = 1 × 10−6 (STP) cm3/(cm2 s cmHg); 1 barrer = 10−10 cm3 (STP) cm/(cm2 s cmHg); STP: standard temperature and pressure.