TABLE 1.
Binding constant (K b) and number of average binding sites (n) of the Fe complex with DNA at different temperatures.
T (K) | K sv (M−1 s−1) | R 2 | K b (M−1) | n | R 2 | ∆H (kJ/mol) | ∆S (J/mol) | ∆G (kJ/mol) |
---|---|---|---|---|---|---|---|---|
298 | 5.649×1012 | 0.996 | 5.957×105 | 1.196 | 0.996 | −12.299 | 65.967 | −32.957 |
303 | 5.445×1012 | 0.997 | 5.527×105 | 1.194 | 0.998 | −33.287 | ||
308 | 4.405×1012 | 0.997 | 5.004×105 | 1.197 | 0.998 | −33.616 |