EIS results calculated from fitting the Nyquist plots in Fig. 4(A) with the modified Randles circuit.20 Values and errors are averages and standard deviations of three measurements.
| Fe at% | a | R s (Ω) | R ct (Ω) | C dl (μF cm−2) | k 0 (cm s−1) |
|---|---|---|---|---|---|
| ta-C | 0.89 ± 0.00 | 16 ± 2 | 841 ± 160 | 0.3 ± 0.0 | 0.002 ± 3 × 10−4 |
| 2 | 0.76 ± 0.07 | 18 ± 1 | 4.0 ± 0.6 | 5.0 ± 0.2 | 0.37 ± 0.05 |
| 5 | 0.82 ± 0.05 | 18 ± 1 | 2.7 ± 0.5 | 5.9 ± 1.0 | 0.54 ± 0.11 |
| 10 | 0.84 ± 0.05 | 22 ± 8 | 1.6 ± 0.3 | 7.0 ± 0.4 | 0.94 ± 0.16 |