Peak assignments for nucleic acidsa.
Contributing group | Frequency (cm−1) | Assignment |
---|---|---|
Base | 726 | Ring breathing of A58 |
668, 746, 785 | Ring breathing of T58 | |
668 | Ring breathing of G58 | |
781, 785 | Ring breathing of C58 | |
785 | Ring breathing of U58 | |
1257 | Ring mode (C, T)58 | |
1336 | Ring mode (A, G); A form of DNA59 | |
1485 | Ring stretching (G, A) A form of DNA59 | |
1576 | Ring stretching (A, G); A form of DNA59 | |
Backbone | 807 | ν as(O–P–O), νs(O–P–O); A-DNA52 |
1099 | ν s(PO2−); A-DNA52 | |
1415 | df(CH2); A-DNA52 | |
784 | ν s(O–P–O); B-DNA52 | |
830 | ν as(O–P–O); B-DNA52 | |
1090 | ν s(PO2−); B-DNA52 | |
1420 | df(CH2); B-DNA52 | |
748 | ν s(O–P–O); Z-DNA | |
792 | ν as(O–P–O); Z-DNA | |
810 | ν as(O–P–O); Z-DNA | |
1095 | ν s(PO2−); Z-DNA | |
1425 | df(CH2); Z-DNA |
ν: stretching (s: symmetric, as: asymmetric), b: bending, t: twisting, df: deformation, A: adenine, T: thymine, C: cytosine, G: guanine, U: uracil, A-DNA: A-form of DNA, B-DNA: B form of DNA, Z-DNA: Z form of DNA.