Skip to main content
. 2018 Jul 20;8(46):25888–25908. doi: 10.1039/c8ra04491k

Peak assignments for nucleic acidsa.

Contributing group Frequency (cm−1) Assignment
Base 726 Ring breathing of A58
668, 746, 785 Ring breathing of T58
668 Ring breathing of G58
781, 785 Ring breathing of C58
785 Ring breathing of U58
1257 Ring mode (C, T)58
1336 Ring mode (A, G); A form of DNA59
1485 Ring stretching (G, A) A form of DNA59
1576 Ring stretching (A, G); A form of DNA59
Backbone 807 ν as(O–P–O), νs(O–P–O); A-DNA52
1099 ν s(PO2); A-DNA52
1415 df(CH2); A-DNA52
784 ν s(O–P–O); B-DNA52
830 ν as(O–P–O); B-DNA52
1090 ν s(PO2); B-DNA52
1420 df(CH2); B-DNA52
748 ν s(O–P–O); Z-DNA
792 ν as(O–P–O); Z-DNA
810 ν as(O–P–O); Z-DNA
1095 ν s(PO2); Z-DNA
1425 df(CH2); Z-DNA
a

ν: stretching (s: symmetric, as: asymmetric), b: bending, t: twisting, df: deformation, A: adenine, T: thymine, C: cytosine, G: guanine, U: uracil, A-DNA: A-form of DNA, B-DNA: B form of DNA, Z-DNA: Z form of DNA.