Influence of Mo(CO)6 on the nitrene transfera.
| |||
|---|---|---|---|
| Entry | Cu(BF4)2·H2O | Mo(CO)6 | Yieldb [%] |
| 1 | + | + | 64 |
| 2 | + | − | 6 |
| 3 | − | + | — |
| 4 | − | − | — |
Conditions: styrene (0.2 mmol), Cu(BF4)2·H2O (0.1 eq.); neocuproine (0.1 eq.); Ph-I N-SO2-o-NO2-Ph (1.5 eq.); Mo(CO)6 (0.25 eq.); MeNO2 (0.6 mL).
Yields were determined by 1H NMR using 1,3,5-trimethoxybenzene as internal standard.