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. 2018 Sep 3;8(54):30860–30867. doi: 10.1039/c8ra05947k

Catalyst screening for the carbonation of EMSa.

graphic file with name c8ra05947k-u1.jpg
Entry Metal salt PTC Yield (%)
1 KI 0
2 KI Ethylene glycol <5
3 KI Triethylene glycol 10
4 KI Tetraethylene glycol 52
5 KI PEG-200 55
6 KI PEG-400 79
7 KI PEG-600 78
8 KI PEG-800 78
9 KI PEG-1000 74
10 KI PEG-2000 74
11 KI PEG-4000 78
12 NaI PEG-400 65
13 CaI2 PEG-400 0
14 ZnI2 PEG-400 0
15 KBr PEG-400 0
a

Reaction conditions: reaction temperature: 120 °C; reaction time: 18 h; CO2 pressure: 1.0 MPa; stirring speed: 400 rpm; catalyst loading: 5 mol%; PTC concentration: 5 mol%; EMS: 5.0 g.