Catalyst screening for the carbonation of EMSa.
Entry | Metal salt | PTC | Yield (%) |
---|---|---|---|
1 | KI | — | 0 |
2 | KI | Ethylene glycol | <5 |
3 | KI | Triethylene glycol | 10 |
4 | KI | Tetraethylene glycol | 52 |
5 | KI | PEG-200 | 55 |
6 | KI | PEG-400 | 79 |
7 | KI | PEG-600 | 78 |
8 | KI | PEG-800 | 78 |
9 | KI | PEG-1000 | 74 |
10 | KI | PEG-2000 | 74 |
11 | KI | PEG-4000 | 78 |
12 | NaI | PEG-400 | 65 |
13 | CaI2 | PEG-400 | 0 |
14 | ZnI2 | PEG-400 | 0 |
15 | KBr | PEG-400 | 0 |
Reaction conditions: reaction temperature: 120 °C; reaction time: 18 h; CO2 pressure: 1.0 MPa; stirring speed: 400 rpm; catalyst loading: 5 mol%; PTC concentration: 5 mol%; EMS: 5.0 g.