Table 2.

Peak fit parameters of the Ge 3d signal resulting from the XPS analysis shown in Fig. 4.

Figure 4	$\mathrm{\Theta }$ ${(}^{\circ })$	Comp.	$E_{\mathrm{kin}}$ $(\text{eV})$	$E_{\mathrm{SOC}}$ $(\text{eV})$	$\mathrm{FWHM}$ $(\text{eV})$	$\alpha$	$A_{\mathrm{rel}}$ $(\%)$
(a)	0	${\text{Ag}}_2\text{Ge}$	107.45	0.56	0.33	0.12	86.7
		SP	107.28	0.56	0.33	0.12	13.3
	60	${\text{Ag}}_2\text{Ge}$	107.46	0.56	0.50	0.12	84.0
		SP	107.29	0.56	0.50	0.12	16.0
(b)	0	SP1	107.46	0.56	0.50	0.13	29.7
		SP2	107.08	0.56	0.50	0.13	26.3
		SP3	106.82	0.56	0.50	0.13	44.0
	60	SP1	107.45	0.56	0.50	0.13	31.2
		SP2	107.07	0.56	0.50	0.13	21.2
		SP3	106.81	0.56	0.50	0.13	47.7
(c)	0	SP	107.26	0.57	0.40	0.08	43.7
		germ.	107.10	0.57	0.51	0.08	56.4
	60	SP	107.27	0.57	0.40	0.08	33.1
		germ.	107.12	0.57	0.51	0.08	66.9
(d)	0	germ.	107.18	0.57	0.54	0.08	100.0
	60	germ.	107.18	0.57	0.54	0.08	100.0

Each component consists of a convolution of a Doniach-Sunjic profile with asymmetry parameter $\alpha$ and a Gaussian.