Conversion of fructose to 5-HMF with different solventsa.
Entry | Solvent | Experimental parameter | ||
---|---|---|---|---|
Conversion/% | Yield/% | Selectivity/% | ||
1 | DMSO | 100 | 96.7 | 96.7 |
2 | DMA | 87.1 | 31.3 | 35.9 |
3 | DMF | 91.8 | 33.5 | 36.5 |
4 | NMP | 96.7 | 70.3 | 72.8 |
5 | Acetone | 89.5 | 33.9 | 37.8 |
6 | MIBK | 91.5 | 1.3 | 1.5 |
7 | sec-Butanol | 92.8 | 26.3 | 28.3 |
8 | n-Butanol | 22.4 | 0.9 | 4.1 |
9 | [EMIM]Br | 50.6 | 5.3 | 10.5 |
10 | H2O | 59.9 | 7.8 | 13.0 |
11 | DMSO/H2O (4 : 1) | 82.9 | 5.9 | 7.2 |
Conditions: 56 mM fructose, 50 mg NbPW-06, 80 °C, 3 h.