ILs (imidazolium-based) and corresponding recovery methods reported in literature.
Methods | Imidazolium | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
Cl−, Br− | BF4− | PF6− | MS− | TfO− | Tf2N− | O2CH−, Ac−, Pr− | SO42−, NO2− | DMP− | BETI− | FeCl4− | ||
Distillation | Distillation of volatile compounds | ✓45,78–81 | ✓46 | ✓46 | ✓46 | ✓46 | ✓46 | ✓27,81,84,85 | ||||
Distillation through reaction of ILs | ✓44,100 | |||||||||||
Extraction | Extraction with water | ✓65,110,111 | ✓51 | |||||||||
Extraction with organic solvents | ✓78,116 | ✓114,115 | ✓117 | ✓118 | ✓113 | ✓69 | ||||||
Extraction with scCO2 | ✓50,130 | ✓28,50,123,124,127–129 | ✓50 | ✓50,125,126 | ||||||||
Adsorption | Adsorption by ACs | ✓48,55,70,132–137,149 | ✓48,70 | ✓21,48,70,131,136 | ✓48,132 | ✓48,70,132,133 | ✓48,70,132,133 | ✓132 | ||||
Adsorption by soils and sediments | ✓47,139,141,143–146,149 | ✓140,142 | ✓142 | |||||||||
Adsorption by ion exchange resins | ✓149,150,152 | ✓152 | ✓152 | ✓151,153 | ||||||||
Membrane separation | Pressure-driven membrane techniques | ✓166 | ✓30,166 | ✓30 | ✓72 | |||||||
Pervaporation | ✓171 | ✓172 | ||||||||||
Membrane distillation | ✓173 | ✓68 | ||||||||||
Electrodialysis | ✓176–179 | |||||||||||
Aqueous two-phase extraction | ATPE based on chemicals addition | ✓31,62,184–187,189,193–195 | ✓53,190,195,196,199 | ✓191 | ✓191,192,194,199 | ✓188,194 | ✓191 | |||||
Crystallization | Solution crystallization | ✓203 | ✓71 | |||||||||
Melt crystallization | ✓32 | ✓54 | ✓54 | ✓54,206 | ✓206 | |||||||
Pressure-induced crystallization | ✓202 | ✓214 | ||||||||||
Force field | Gravity separation | ✓43 | ||||||||||
Centrifugation | ✓66 | ✓66 | ||||||||||
Magnetic separation | ✓33,218 |