Details of kinetic parameter and coefficient of determination for various kinetic models for the adsorption of RB onto MNP-PANI-DICAT.
Kinetic models | Parameters | Materials | ||
---|---|---|---|---|
MNP | MNP-PANI | MNP-PANI-DICAT | ||
q e,exp (mg g−1) | 1.0798 | 2.4416 | 4.8116 | |
Pseudo-first-order | q e,cal (mg g−1) | 0.1532 | 0.0720 | 0.1622 |
k 1 (min−1) | 0.0085 | −0.0058 | −0.0023 | |
R 2 | 0.2415 | 0.0867 | 0.0058 | |
Δq (%) | 32.4340 | 36.6820 | 36.5220 | |
Relative error (%) | 85.8120 | 97.0530 | 96.6290 | |
Pseudo-second-order | q e, cal (mg g−1) | 1.0267 | 2.4414 | 4.8379 |
k 2 (g mg−1 min−1) | 3.4149 | 0.4047 | 0.4172 | |
h (mg g−1 min−1) | 3.5597 | 2.4119 | 9.7656 | |
t 1/2 (min) | 3.3261 | 0.1658 | 0.0862 | |
R 2 | 0.9992 | 0.9998 | 1.0000 | |
Δq (%) | 1.8580 | 0.0023 | 0.2066 | |
Relative error (%) | 4.9158 | 0.0061 | 0.5466 | |
Elovich equation | q e cal (mg g−1) | 1.0215 | 2.3818 | 4.7726 |
β (g mg−1) | 909.0910 | 20.2840 | 16.6945 | |
α (mg g−1 min−1) | — | 7.8713 × 1017 | 3.9980 × 1031 | |
R 2 | 0.0190 | 0.9016 | 0.7433 | |
Δq (%) | 2.0400 | 0.9242 | 0.3064 | |
Relative error (%) | 5.3974 | 2.4452 | 0.8105 | |
Intra-particle diffusion | C (mg g−1) | 1.0185 | 2.2497 | 4.6093 |
K (mg g−1 min−1) | 0.0004 | 0.0153 | 0.0189 | |
R 2 | 0.0019 | 0.8418 | 0.7232 | |
External diffusion | k ext (1/min) | 7.0 × 10−6 | 0.0003 | 0.0064 |
C (mg g−1) | −0.2185 | −0.6225 | −2.9960 | |
R 2 | 0.0026 | 0.7219 | 0.6448 |