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. 2018 Sep 26;8(58):33180–33192. doi: 10.1039/c8ra06687f

Details of kinetic parameter and coefficient of determination for various kinetic models for the adsorption of RB onto MNP-PANI-DICAT.

Kinetic models Parameters Materials
MNP MNP-PANI MNP-PANI-DICAT
q e,exp (mg g−1) 1.0798 2.4416 4.8116
Pseudo-first-order q e,cal (mg g−1) 0.1532 0.0720 0.1622
k 1 (min−1) 0.0085 −0.0058 −0.0023
R 2 0.2415 0.0867 0.0058
Δq (%) 32.4340 36.6820 36.5220
Relative error (%) 85.8120 97.0530 96.6290
Pseudo-second-order q e, cal (mg g−1) 1.0267 2.4414 4.8379
k 2 (g mg−1 min−1) 3.4149 0.4047 0.4172
h (mg g−1 min−1) 3.5597 2.4119 9.7656
t 1/2 (min) 3.3261 0.1658 0.0862
R 2 0.9992 0.9998 1.0000
Δq (%) 1.8580 0.0023 0.2066
Relative error (%) 4.9158 0.0061 0.5466
Elovich equation q e cal (mg g−1) 1.0215 2.3818 4.7726
β (g mg−1) 909.0910 20.2840 16.6945
α (mg g−1 min−1) 7.8713 × 1017 3.9980 × 1031
R 2 0.0190 0.9016 0.7433
Δq (%) 2.0400 0.9242 0.3064
Relative error (%) 5.3974 2.4452 0.8105
Intra-particle diffusion C (mg g−1) 1.0185 2.2497 4.6093
K (mg g−1 min−1) 0.0004 0.0153 0.0189
R 2 0.0019 0.8418 0.7232
External diffusion k ext (1/min) 7.0 × 10−6 0.0003 0.0064
C (mg g−1) −0.2185 −0.6225 −2.9960
R 2 0.0026 0.7219 0.6448