Table 3. Bond Distances and Angles for the Interactions (O–H···O, O–H···π, C–H···π, and C–H···F) in I–VI.

structure	#	H-bond	D–H (Å)	H···A (Å)	D···A (Å)	∠DHA (deg)
I	1	O(12B)–H(12B)···O(12A)	0.78(3)	1.93(3)	2.700(3)	171(5)
	2	O(12A)–H(12A)···O(11A)	0.77(3)	2.03(3)	2.792(3)	169(5)
	3	O(11A)–H(11A)···O(11B)	0.79(3)	2.01(3)	2.773(3)	163(5)
II	1	O(12B)–H(12B)···O(20)	0.88(3)	1.80(3)	2.670(3)	171(3)
	2	O(20)–H(20b)···O(11B)	0.85(2)	2.15(3)	2.940(3)	155(4)
	3	O(20)–H(20a)···O(12A)	0.85(2)	2.01(2)	2.857(2)	174(4)
	4	O(12A)–H(12A)···O(12B)	0.86(3)	1.97(3)	2.776(2)	155(2)
	5	O(11B)–H(11B)···π	0.85(3)	2.76(3)	3.56(2)	157(4)
III	1	O(11)–H(11)···O(12)	0.87(14)	2.14(15)	2.90(4)	151(7)
	2	O(12)–H(12)···O(11)	1.07(11)	1.70(11)	2.77(2)	172(8)
IV	1	O(11B)–H(11B)···O(12A)	0.84(2)	1.98(2)	2.742(2)	151(2)
	2	O(12A)–H(12A)···O(12B)	0.89(2)	1.96(2)	2.814(2)	161(2)
	3	O(12B)–H(12B)···O(11A)	0.85(2)	2.19(2)	2.979(2)	155(2)
	4	O(11A)–H(11A)···O(11B)	0.84(2)	2.00(2)	2.819(2)	164(2)
	5	C(6B)–H(6B)···F(A2)	0.95(2)	2.50(2)	3.34(2)	146(2)
	6	C(6A)–H(6A) ···Cg	0.95(2)	3.34(2)	4.09(2)	137(2)
V	1	O(12)–H(12)···O(11)	0.78(2)	1.93(2)	2.700(2)	171(4)
	2	O(11)–H(11)···π	0.84(2)	2.32(2)	3.050(2)	145(3)
VI	1	O(23)–H(23)···O(12)	0.886(18)	1.88(2)	2.763(2)	175(3)
	2	O(12)–H(12)···O(11)	0.876(17)	1.84(2)	2.706(2)	172(2)
	3	O(11)–H(11)···O(23)	0.879(17)	1.89(2)	2.763(2)	171(2)
	4	C(6)–H(6)···F(13b)	0.93(2)	2.63	3.473	150.6