Table 3. Kinetic Parameters of the Adsorption of Hg over PAMC from Water Solutionsa.
Lagergren
first-order |
pseudo-second-order |
W-M
intraparticle diffusion |
||||||||
---|---|---|---|---|---|---|---|---|---|---|
T (K) | qe, exp (mg/g) | k1 (min–1) | qe, cal (mg/g) | R2 | k2 g/mg.min | qe, cal (mg/g) | R2 | Kid mg/g.min1/2 | C (mg/g) | R2 |
298 | 37.2 | 0.0508 | 47.53 | 0.9307 | 0.001 | 45.25 | 0.9906 | 3.7082 | 4.0497 | 0.9901 |
318 | 38.4 | 0.0519 | 49.77 | 0.9422 | 0.001 | 48.31 | 0.9938 | 3.7588 | 5.013 | 0.9823 |
338 | 39.6 | 0.0523 | 45.41 | 0.9684 | 0.002 | 46.51 | 0.9946 | 1.6798 | 24.008 | 0.9484 |
Hg conc. = 200 ppm.