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. 2022 Apr 14;7(16):14089–14101. doi: 10.1021/acsomega.2c00652

Figure 1.

Figure 1

(a) Left: 2D layered MOF of 1; right: 2D topological representation of 1 with BDC2– (red lines) and bpym (green lines) as linear linkers. The guest bpym, five water molecules, and hydrogen atoms are omitted for clarity. (b) 3D supramolecular network of 1 assembled by 2D layered MOFs viewed along the c axis. (c) 1D hydrogen-bonded polymeric chains assembled by five guest water molecules in the 3D supramolecular network using puckered hydrogen-bonded (H2O)4 tetramers and (H2O)6 hexamers as building units. (d) Guest bpym (green color) molecules in the 3D supramolecular network.