Table 2. Interfacial Liquid Layer Volume (VIL), Total Liquid Phase Volume (V0), Surface Area (As), Pore Volume (Vpore), and Bonding Density (ρ) for the Capcell Pak C18 Columns.
| acetonitrile |
methanol |
|||||
|---|---|---|---|---|---|---|
| ϕCH3CNBL | UG120 | UG300 | ϕCH3OHBL | UG120 | UG300 | |
| 0.00 | 0.424 ± 0.032 | 0.265 ± 0.022 | 0.00 | 0.430 ± 0.029 | 0.265 ± 0.022 | |
| 0.01 | 0.468 ± 0.024 | 0.291 ± 0.032 | 0.01 | 0.440 ± 0.019 | 0.321 ± 0.013 | |
| VIL (mL) | 0.05 | 0.498 ± 0.014 | 0.320 ± 0.026 | 0.05 | 0.463 ± 0.030 | 0.274 ± 0.031 |
| 0.09 | 0.516 ± 0.026 | 0.352 ± 0.009 | 0.09 | 0.485 ± 0.045 | 0.259 ± 0.042 | |
| 0.19 | 0.563 ± 0.021 | 0.384 ± 0.027 | 0.19 | 0.470 ± 0.028 | 0.253 ± 0.047 | |
| V0 (mL) | 2.744 | 3.158 | 2.659 | 3.158 | ||
| As (m2 column–1) | 378.05 | 248.86 | 399.13 | 248.86 | ||
| Vpore (mL) | 1.113 | 1.641 | 1.175 | 1.641 | ||
| ρ (μmol m–2)a | 2.5 | 3.7 | 2.5 | 3.7 | ||
manufacturer’s data.