Composition of photocurable thiol-epoxy resin formulations comprising a stoichiometric concentration of epoxy and thiol groups.
Sample | epoxy-NBEa/mol% | epoxy-GMEa/mol% | Molar ratio epoxy/thiol groups | ITX/wt% | PLB/wt% | Tg/°C | Gel content/% |
---|---|---|---|---|---|---|---|
PI2 | 100 | 0 | 1 : 1 | 2 | 2 | — | — |
PI3 | 100 | 0 | 1 : 1 | 3 | 3 | — | — |
PI4 | 100 | 0 | 1 : 1 | 4 | 4 | 15 | 98 |
PI5 | 100 | 0 | 1 : 1 | 5 | 5 | — | — |
PI4-G5 | 95 | 5 | 1 : 1 | 4 | 4 | 13 | 95 |
PI4-G7 | 93 | 7 | 1 : 1 | 4 | 4 | 11 | 89 |
mol% related to the total epoxy resin.