The relevant electrochemical and electrocatalytic data for 1 and 2 in N2 atmosphere.
Complex | Atmosphere | E pc a (V) | i p (μA) | i cat b (μA) | i cat/ip |
---|---|---|---|---|---|
1 | N2 | 2.02 | 64.17 | 208.25 | 3.24 |
2 | N2 | 1.98 | 67.14 | 428.51 | 6.21 |
All data for 1 and 2 (1 mM) are versus Ag/AgNO3 in 0.1 M n-Bu4NPF6/MeCN at a scan rate of 200 mV s−1.
i cat is the catalytic current at the highest concentration of HOAc (8 mM).