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. Author manuscript; available in PMC: 2022 Dec 22.
Published in final edited form as: J Am Chem Soc. 2021 Dec 13;143(50):21402–21409. doi: 10.1021/jacs.1c10757

Figure 4.

Figure 4.

Tuning inter-co-catalyst distance using template strands with single-stranded spacers. (a) Co-catalyst-bearing ssDNA oligomers (red and blue) were annealed to a template ssDNA (black), bringing the co-catalysts into proximity. (b) 2-Napthalenemethanol oxidation by 3-strand DNA-scaffolded Cu-TEMPO catalysts with polythymidine spacers of varying lengths. Data are plotted as the mean ± standard deviation of 3 independent experiments.