Spectroscopic data of 5-N-arylaminothiazoles and zinc–thiazole complexes in a solid state.
Thiazole | λ abs (nm) | λ ex (nm) | λ em a (nm) | ν ss [cm−1] (nm) | φ F b | χ 2 c | τ c (ns) |
---|---|---|---|---|---|---|---|
4b | 442 | 439 | 495 | [2411] (53) | 0.21 | 1.66 | 2.53 |
4c | 444 | 437 | 542 | [3438] (80) | 0.06 | 3.5 | 2.47 |
4d | 444 | 437 | 475 | [1469] (31) | 0.21 | 1.56 | 2.77 |
4e | 427 | 428 | 469 | [2097] (42) | 0.15 | 1.36 | 1.91 |
41 | 404 | 431 | 475 | [3609] (71) | 0.52 | 1.54 | 3.03 |
8a | 440 | 370 | 611 | [6360] (171) | 0.02 | 3.21 | 121 |
8b | 440 | 365 | 550 | [4545] (110) | 0.05 | 2.41 | 1.99 |
8c | 452 | 492 | 548 | [3875] (96) | 0.02 | 2.66 | 0.23 |
Excited in λmax.
Absolute fluorescence of quantum yield.
Excited at 365 nm.