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. Author manuscript; available in PMC: 2022 Dec 29.
Published in final edited form as: J Am Chem Soc. 2021 Dec 16;143(51):21637–21647. doi: 10.1021/jacs.1c10051

Figure 1.

Figure 1.

Cleavage of peroxo O–O bonds to give high-spin FeIV(O) intermediates in select nonheme iron enzymes and formation of a high-spin FeIV(O) intermediate in Fe-ZSM-5.