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. 2022 May 17;12(24):15020–15037. doi: 10.1039/d2ra02293a

Catalytic activity of the nanocatalyst for the reduction of nitrobenzene to aniline with N2H4·H2O 80%a.

graphic file with name d2ra02293a-u1.jpg
Entry R Product Time (min) Yield (%)
1 H graphic file with name d2ra02293a-u2.jpg 10 98
2 4-OH graphic file with name d2ra02293a-u3.jpg 30 90
3 4-NH2 graphic file with name d2ra02293a-u4.jpg 40 98
4 2-OH graphic file with name d2ra02293a-u5.jpg 15 97
5 4-COMe graphic file with name d2ra02293a-u6.jpg 20 92
6 3-Me graphic file with name d2ra02293a-u7.jpg 35 90
7 4-Me graphic file with name d2ra02293a-u8.jpg 30 91
8 2-NH2 graphic file with name d2ra02293a-u9.jpg 60 95
9 3-COMe graphic file with name d2ra02293a-u10.jpg 45 94
10 3-CHO graphic file with name d2ra02293a-u11.jpg 60 93
11 3-OH graphic file with name d2ra02293a-u12.jpg 30 96
12b 3-NH2-5-NO2 graphic file with name d2ra02293a-u13.jpg 20 92
a

All reactions were carried out with 1 mmol of nitroarene, 2 mmol of N2H4·H2O 80% and 20 mg of rGO@Fe3O4/ZrCp2Clx in refluxing EtOH (2 mL).

b

In this reaction 3 mmol of N2H4·H2O 80% was used.