Catalytic activity of the nanocatalyst for the reduction of nitrobenzene to aniline with N2H4·H2O 80%a.
| ||||
|---|---|---|---|---|
| Entry | R | Product | Time (min) | Yield (%) |
| 1 | H |
|
10 | 98 |
| 2 | 4-OH |
|
30 | 90 |
| 3 | 4-NH2 |
|
40 | 98 |
| 4 | 2-OH |
|
15 | 97 |
| 5 | 4-COMe |
|
20 | 92 |
| 6 | 3-Me |
|
35 | 90 |
| 7 | 4-Me |
|
30 | 91 |
| 8 | 2-NH2 |
|
60 | 95 |
| 9 | 3-COMe |
|
45 | 94 |
| 10 | 3-CHO |
|
60 | 93 |
| 11 | 3-OH |
|
30 | 96 |
| 12b | 3-NH2-5-NO2 |
|
20 | 92 |
All reactions were carried out with 1 mmol of nitroarene, 2 mmol of N2H4·H2O 80% and 20 mg of rGO@Fe3O4/ZrCp2Clx in refluxing EtOH (2 mL).
In this reaction 3 mmol of N2H4·H2O 80% was used.