TABLE 3.

¹H and ¹³C NMR data for 2-amino-5-chlorophenol and 5-chloropicolinic acid in CD₃OD

2-Amino-5-chlorophenol			5-Chloropicolinic acid
1H chemical shifts (ppm)	1H-1H coupling constants (Hz)	13C chemical shifts (ppm)	1H chemical shifts (ppm)	1H-1H coupling constants (Hz)	13C chemical shifts (ppm)	One-bond 13C-1H coupling constants (Hz)a
H-3 6.70	(3-4) 8.3	C-1 147.2	H-3 8.18	(3-4) 8.4	C-2 147.6
H-4 6.64	(4-6) 2.3	C-2 135.5	H-4 8.08	(3-6) 0.7	C-3 127.3	168.0
H-6 6.72		C-3 117.6	H-6 8.70	(4-6) 2.4	C-4 138.7	170.5
		C-4 120.5			C-5 137.1
		C-5 123.8			C-6 149.4	186.3
		C-6 115.4			C-7 166.6

^aThe values of the one-bond ¹³C-¹H coupling constants were estimated from the residual cross peaks in the ¹H-detected long-range ¹³C-¹H correlation.