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. 2022 May 5;144(19):8467–8473. doi: 10.1021/jacs.2c02261

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© 2022 The Authors. Published by American Chemical Society

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Subcomponent self-assembly of Cd^II₄Cu^I₄L₄ cages (a) 3 and (b) 4. Externally coordinated acetonitrile molecules are omitted for clarity. (c) Crystal structure of 3 with inset showing one Cd^IICu^I vertex. (d) Crystal structure of 4. Disorder, anions, solvent of crystallization, and hydrogen atoms are omitted for clarity.