Excitation wavelength-dependent emissions of the 4-hydroxy benzohydrazide-based biopolymer/O-carboxymethyl chitosan Schiff Cu(ii) complexes.
| Name of the compounds | Catalytic dosage (mg) | Excitation wavelength λexi (nm) | Emission wavelength λemi (nm) | Stokes shift | PL intensity | |
|---|---|---|---|---|---|---|
| [(SB1)–Cu(OAc)2] | 2 | 386 | 442 | 56 | 793 | Increase |
| 4 | 385 | 440 | 55 | 921 | ||
| 6 | 420 | 477 | 57 | 322 | Decrease | |
| 8 | 423 | 476 | 54 | 265 | ||
| [(SB2)–Cu(OAc)2] | 2 | 398 | 452 | 51 | 469 | Increase |
| 4 | 399 | 451 | 52 | 588 | ||
| 6 | 400 | 450 | 50 | 612 | ||
| 8 | 405 | 454 | 49 | 377 | Decrease | |