Table 1.
Chemical composition Myrtus communis L. leaves essential oil. Results are expressed as mean area percentage (%) ± standard deviation (S.D.) of three independent determinations (n = 3)
| N | Compounds | % | KIa | KIb | Identificationc |
|---|---|---|---|---|---|
| 1 | 3Z- Hexenal | 0.1 ± 0.02 | 744 | 798 | 1,2 |
| 2 | 2E- Hexenal | 0.1 ± 0.03 | 747 | 855 | 1,2 |
| 3 | n-Nonane | T | 752 | 900 | 1,2 |
| 4 | Isobutyl isobutyrate | 0.1 ± 0.02 | 758 | 911 | 1,2 |
| 5 | Tricyclene | T | 849 | 926 | 1,2 |
| 6 | Heptyl isobutanoate | 3.2 ± 0.3 | 855 | 1250 | 1,2 |
| 7 | α-Thujene | 0.4 ± 0.01 | 861 | 930 | 1,2,3 |
| 8 | α-Pinene | 14.7 ± 1.2 | 868 | 939 | 1,2,3 |
| 9 | Camphene | T | 877 | 954 | 1,2,3 |
| 10 | Sabinene | 0.3 ± 0.03 | 902 | 975 | 1,2,3 |
| 11 | β-Pinene | 0.3 ± 0.04 | 921 | 979 | 1,2,3 |
| 12 | δ-3-Carene | 0.3 ± 0.02 | 929 | 1011 | 1,2,3 |
| 13 | β- Myrcene | 0.1 ± 0.01 | 930 | 990 | 1,2,3 |
| 14 | Butyl-2-methylbutanoate | 0.2 ± 0.01 | 933 | - | 1,2 |
| 15 | α-Terpinene | 0.1 ± 0.02 | 941 | 1017 | 1,2,3 |
| 16 | 1,8-Cineole | 21.9 ± 2.3 | 957 | 1031 | 1,2,3 |
| 17 | E-β-Ocimene | 1.1 ± 0.5 | 966 | 1050 | 1,2 |
| 18 | γ-Terpinene | 0.4 ± 0.03 | 1006 | 1059 | 1,2,3 |
| 19 | Terpinolene | 0.1 ± 0.02 | 1008 | 1088 | 1,2,3 |
| 20 | dehydro-Linalool | T | 1013 | 1090 | 1,2 |
| 21 | Linalool | 9.1 ± 1.6 | 1026 | 1096 | 1,2,3 |
| 22 | Myrcenol | 0.2 ± 0.03 | 1028 | 1122 | 1,2 |
| 23 | cis-p-Menth-2-n-1-ol | 0.1 ± 0.02 | 1033 | 1121 | 1,2 |
| 24 | allo Ocimene | 0.8 ± 0.04 | 1048 | 1132 | 1,2 |
| 25 | trans-Pinocarveol | 0.1 ± 0.01 | 1054 | 1139 | 1,2 |
| 26 | 3E-6Z-Nonadienol | 0.1 ± 0.03 | 1065 | 1153 | 1,2 |
| 27 | neo-Menthol | T | 1082 | 1165 | 1,2 |
| 28 | δ-Terpineol | T | 1084 | 1166 | 1,2,3 |
| 29 | Terpinen-4-ol | 0.4 ± 0.05 | 1092 | 1177 | 1,2,3 |
| 30 | α-Terpineol | 2.3 ± 0.4 | 1101 | 1188 | 1,2,3 |
| 31 | Myrtenal | 0.1 ± 0.04 | 1103 | 1195 | 1,2,3 |
| 32 | Myrtenol | 0.8 ± 0.03 | 1106 | 1195 | 1,2 |
| 33 | Methyl chavicol | 0.2 ± 0.05 | 1108 | 1196 | 1,2 |
| 34 | Iso-dihydro-carveol | T | 1127 | 1214 | 1,2 |
| 35 | Fraganol | 0.1 ± 0.02 | 1144 | 1215 | 1,2 |
| 36 | cis-Myrtanol | T | 1160 | 1253 | 1,2 |
| 37 | Linalool acetate | 0.8 ± 0.06 | 1167 | 1257 | 1,2 |
| 38 | δ-Octalactone | T | 1177 | 1278 | 1,2 |
| 39 | Isobornyl acetate | T | 1191 | 1285 | 1,2 |
| 40 | trans-Pinocarvyl acetate | 0.6 ± 0.03 | 1199 | 1298 | 1,2 |
| 41 | Carvacrol | 0.1 ± 0.02 | 1214 | 1299 | 1,2,3 |
| 42 | Myrtenyl acetate | 29.8 ± 2.4 | 1236 | 1326 | 1,2 |
| 43 | iso-dihydro-Carveol acetate | 0.3 ± 0.02 | 1237 | 1329 | 1,2 |
| 44 | Carvyl acetate | 0.1 ± 0.03 | 1241 | 1342 | 1,2 |
| 45 | α-Terpinyl acetate | 0.5 ± 0.04 | 1250 | 1349 | 1,2 |
| 46 | Citronellyl acetate | 0.1 ± 0.02 | 1257 | 1352 | 1,2 |
| 47 | Geranyl acetate | 2.6 ± 0.5 | 1268 | 1381 | 1,2,3 |
| 48 | Methyl eugenol | 0.9 ± 0.02 | 1302 | 1403 | 1,2 |
| 49 | Z-Caryophyllene | 1.3 ± 0.06 | 1306 | 1408 | 1,2,3 |
| 50 | γ-Elemene | 0.1 ± 0.01 | 1323 | 1436 | 1,2,3 |
| 51 | α-Humulene | 1.1 ± 0.02 | 1340 | 1454 | 1,2,3 |
| 52 | p-Menth(1,8 dien)-9-ol | 0.4 ± 0.02 | 1343 | 1374 | 1,2,3 |
| 53 | Bisabolol | 0.2 ± 0.08 | 1347 | 1685 | 1,2,3 |
| 54 | Thymohydro quinone | 0.7 ± 0.06 | 1406 | 1555 | 1,2 |
| 55 | Flavesone | 0.2 ± 0.02 | 1428 | 1547 | 1,2 |
| 56 | Caryophyllene oxide | 0.3 ± 0.02 | 1461 | 1583 | 1,2,3 |
| 57 | Humulene epoxide II | 0.3 ± 0.01 | 1486 | 1608 | 1,2 |
| 58 | allo-Aromadendrene epoxide | 0.1 ± 0.02 | 1504 | 1641 | 1,2 |
| 59 | n-Octadecanol | 0.5 ± 0.06 | 1520 | 2077 | 1,2 |
| Total | 98.4 | ||||
| Monoterpenes hydrocarbons | 18.6 | ||||
| Oxygenated monoterpenes | 71.7 | ||||
| Sesquiterpenes hydrocarbons | 2.6 | ||||
| Oxygenated sesquiterpenes | 1.4 | ||||
| Other | 4.1 |
a, b are the Kovats retention indices determined relative to a series of n-alkanes (C10–C35) on the apolar HP-5 MS and the polar HP Innowax capillary columns, respectively; c identification method: 1 = comparison of the Kovats retention indices with published data; 2 = comparison of mass spectra with those listed in the NIST 02 and Wiley 275 libraries and with published data; 3 = coinjection with authentic compounds; c -: not detected; t = trace (< 0.05%)