Table 2.
1H and 13C NMR data of 3 and 4 in MeOH-d4.
| No. | 3 | 4 | ||
|---|---|---|---|---|
| δC, type | δH, mult (J in Hz) | δC, type | δH, mult (J in Hz) | |
| 1 | 163.2, C | 161.7, C | ||
| 2 | 116.3, CH | 6.88, d (8.6) | 114.7, CH | 6.85, d (8.6) |
| 3 | 132.7, CH | 7.83, dd (2.1, 8.6) | 130.7, CH | 7.79, dd (2.2, 8.6) |
| 4 | 123.7, C | 123.4, C | ||
| 5 | 136.3, CH | 7.98, d (2.1) | 134.9, CH | 7.92, d (2.2) |
| 6 | 111.3, C | 110.8, C | ||
| 7 | 169.6, C | 168.1, C | ||
| 8 | 80.0, C | 76.3, C | ||
| 9 | 97.4, C | 96.3, C | ||
| 10 | 69.8, C | 3.56, dd (6.5, 10.5) | 29.8, CH | 2.85, dd (6.7, 13.5) |
| 11a | 71.1, CH2 | 3.61, s | 65.8, CH2 | 3.65, dd (6.5, 10.5) |
| 11b | 3.56, dd (6.5, 10.5) | |||
| 12 | 26.2, CH3 | 1.53, s | 16.2, CH3 | 1.27, d (1.9) |