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A. Calculated reaction scheme to form atropisomeric deoxyakanthomycin hydrates (1a’ and 1b’). B. sdx gene cluster from Sarocladium oryzae. C. Biosynthetic pathway to form deoxyakanthomycin 1. D. Standards of 12 and 2a/2b (i, ii) and enzymatic reaction of 12 with a SDR (iii) and chemical reaction of 12 with NaBH4 (iv) to form deoxyakanthomycin.
