Table 1. Selected Bond Lengths and Angles for MpyS2Me (M = Pd, Pt).
| PdpyS2Me, 120 K | PdpyS2Me, 250 K | PtpyS2Me, 120 K | PtpyS2Me, 250 K | |
|---|---|---|---|---|
| Selected Bond Lengths [Å] | ||||
| Fe–N(1) | 1.987(3) | 2.219(5) | 1.992(14) | 2.23(3) |
| Fe–N(2) | 1.942(3) | 2.132(4) | 1.943(14) | 2.13(2) |
| Fe–N(3) | 1.943(3) | 2.137(4) | 1.945(14) | 2.11(2) |
| Pd–C(1) | 1.991(3) | 1.991(4) | ||
| Pd–C(2) | 1.992(3) | 1.988(5) | ||
| Pt–C(1) | 1.975(17) | 1.97(2) | ||
| Pt–C(2) | 1.978(17) | 1.93(2) | ||
| C(1)–N(2) | 1.149(4) | 1.131(7) | 1.15(3) | 1.16(3) |
| C(2)–N(3) | 1.153(5) | 1.130(7) | 1.15(3) | 1.21(3) |
| Selected Bond Angles (°) | ||||
| N(1)–Fe–N(2) | 90.06(12) | 90.1(2) | 90.7(6) | 91.6(11) |
| N(1)–Fe–N(3) | 90.13(12) | 90.0(2) | 90.5(6) | 91.0(11) |
| N(2)–Fe–N(3) | 90.01(10) | 90.04(14) | 91.0(6) | 90.2(6) |
| ΣFe | 0.8 | 0.56 | 8.8 | 11.2 |
| C(1)–N(2)–Fe | 179.8(2) | 179.7(5) | 178(2) | 169(2) |
| C(2)–N(3)–Fe | 179.8(3) | 179.9(5) | 177(2) | 178(2) |