. 2022 May 6;10(20):6794–6806. doi: 10.1021/acssuschemeng.2c01180

Table 3. Examples of Preparative Biotransformation Reactions for RedAm-Catalyzed Reductive Amination of Cinnamaldehyde and CAR-RedAm One-Pot Allylation of Amines with Cinnamic Acids Providing Access to 2°and 3° Allylic Amines^a.

All preparative reactions (100 mg of aldehyde or carboxylic acid) were performed with catalytic amounts of cofactors (0.5 mM NADP⁺ and 0.2 mM ATP) using respective cofactor recycling system(s) except [a], which was performed with a stoichiometric supply of ATP (2 equiv).

Table 3. Examples of Preparative Biotransformation Reactions for RedAm-Catalyzed Reductive Amination of Cinnamaldehyde and CAR-RedAm One-Pot Allylation of Amines with Cinnamic Acids Providing Access to 2°and 3° Allylic Aminesa.

Table 3. Examples of Preparative Biotransformation Reactions for RedAm-Catalyzed Reductive Amination of Cinnamaldehyde and CAR-RedAm One-Pot Allylation of Amines with Cinnamic Acids Providing Access to 2°and 3° Allylic Amines^a.