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. 2021 Mar 25;37(13):3808–3816. doi: 10.1021/acs.langmuir.0c02715

Table 1. Hydrodynamic and Electrostatic Properties of the Systems under Study at T = 298 K.

sample D μm2·s–1 (z-average) rh (rg) nm (z-average) Q μe μm·cm·V–1s–1
PEO300 8.55 28.7 (41.6)a 0.37 –0.52 ± 0.02
PS-SO4 7.00 35.0 0.03 –3.2 ± 0.2
PS-SO4 2.38 103.0 0.03 –3.8 ± 0.2
PS-CO2 1.66 148.0 0.03 –3.6 ± 0.1
a

The value between the parentheses corresponds to rg for PEO estimated from rg = 1.45rh. Experiments for several polymers in good solvents report rg = 1.45rh.23 Analytical theories predict rg = 1.59rh.24