Table 3.
Phenolic Compound |
OH | CH | ||
---|---|---|---|---|
H2O | EtOH 50% | H2O | EtOH 50% | |
Hydroxytyrosol and tyrosol derivatives |
||||
Hydroxytyrosol | 28.71 ± 0.42 a | 33.36 ± 0.57 b | 31.20 ± 0.29 c | 33.49 ± 0.40 b |
Tyrosol | 10.63 ± 0.06 a | 21.09 ± 0.12 b | 11.13 ± 0.15 a | 11.09 ± 0.99 a |
Oleuropein | n.d. | 254.38 ± 13.24 a | n.d. | 369.05 ± 23.00 b |
Phenolic acids | ||||
Caffeic acid | n.d. | 2.59 ± 0.47 a | n.d. | 2.27 ± 0.35 a |
Cinnamic acid | 18.45 ± 0.95 a | 19.99 ± 0.46 b | n.d. | n.d. |
p-Coumaric acid | 44.99 ± 3.01 a | 48.41 ± 2.84 a | 20.91 ± 0.91 b | 48.76 ± 1.49 a |
o-Coumaric acid | 23.26 ± 1.24 a | 69.81 ± 1.14 b | 25.45 ± 0.41 a | 48.93 ± 1.02 c |
Ferulic acid | 22.31 ± 1.38 a | 13.83 ± 1.28 b | 23.60 ± 1.22 a | 22.40 ± 0.51 a |
Vanillic acid | 39.51 ± 0.48 a | 72.77 ± 1.11 b | 43.96 ± 1.79 c | 59.41 ± 0.50 d |
3,4-Dihidroxibenzoic acid | 14.20 ± 0.28 a | 17.61 ± 0.94 b | 15.60 ± 0.37 ac | 16.61 ± 0.39 bc |
Syringic acid | n.d. | 42.98 ± 3.74 a | n.d. | n.d. |
Ellagic acid | 142.93 ± 4.49 a | 147.82 ± 3.40 a | 162.01 ± 0.61 b | 148.40 ± 3.85 a |
Homovanillic acid | 103.45 ± 6.24 a | 75.54 ± 0.56 b | 118.62 ± 5.56 c | n.d. |
Rosmarinic acid | 22.05 ± 0.80 a | 62.79 ± 2.27 b | n.d. | n.d. |
Flavonoids | ||||
Apigenin | n.d. | 43.13 ± 1.28 a | n.d. | 42.48 ± 1.31 a |
Rutin | 21.33 ± 0.62 a | 31.46 ± 2.68 b | n.d. | n.d. |
Taxifolin | 83.10 ± 2.23 a | 94.44 ± 4.01 b | 85.82 ± 3.40 a | 89.03 ± 2.42 a |
Naringenin | 125.11 ± 0.56 a | 247.42 ± 10.19 b | 99.96 ± 4.62 c | 137.67 ± 10.14 a |
Hesperidin | 137.30 ± 5.22 a | 93.15 ± 4.24 b | 62.77 ± 1.46 c | 85.75 ± 2.44 b |
Quercetin | 168.62 ± 15.47 a | 134.94 ± 0.89 b | 206.01 ± 6.29 c | 134.14 ± 2.85 b |
Catechin | 63.15 ± 2.39 a | 77.68 ± 1.06 b | 55.29 ± 1.58 c | 49.04 ± 0.78 d |
Stilbene | ||||
Resveratrol | 6.68 ± 1.02 a | 10.34 ± 0.29 b | n.d. | n.d. |
Total | 1075.88 | 1615.54 | 962.23 | 1298.53 |
All the results are expressed as mean ± SD (n = 3) and reported as milligrams of phenolic compound per 100 g of dry material (mg/100 g OP). Different letters in the same row correspond to a statistical difference (95% confidence level) between the samples with respect to analyzed compound; n.d.: not detected.