Table 2.
No | RRIa | RRIb | Compound | ATLv | ATFl | ALLv | ALFl | ADLv | ADFl | AFLv | AFFl | ACLv | ACFl |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | 1032 | 1008–1039 # | α-Pinene | 2.1 | 1.8 | 2.5 | 3.9 | 0.1 | 0.1 | 2.2 | 3.3 | 0.8 | 2.0 |
2 | 1043 | 1011–1063 # | Santolinatriene | 0.7 | 1.7 | 3.5 | 2.2 | 2.4 | |||||
3 | 1076 | 1043–1086 # | Camphene | 7.7 | 7.7 | 7.1 | 5.5 | t | t | 4.0 | 6.0 | 1.6 | 4.1 |
4 | 1189 | 1179 @ | Artemiseole | 2.1 | 3.1 | 2.5 | 7.5 | 1.2 | |||||
5 | 1213 | 1186–1231 # | 1,8-Cineole | 21.8 | 23.8 | 16.3 | 23.1 | 12.5 | 5.7 | 30.0 | 21.9 | ||
6 | 1218 | 1188–1233 # | β-Phellandrene | 1.3 | 2.2 | ||||||||
7 | 1246 | 1211–1251 # | (Z)-β-Ocimene | 4.6 | 9.4 | ||||||||
8 | 1266 | 1232–1267 # | (E)-β-Ocimene | 2.7 | 6.6 | t | |||||||
9 | 1280 | 1246–1291 # | p-Cymene | 1.2 | 1.2 | 0.7 | 0.7 | 0.5 | 0.2 | 3.2 | 2.1 | 0.9 | 0.7 |
10 | 1290 | 1260–1300 # | Terpinolene | t | t | 0.2 | 0.3 | 8.8 | 5.5 | 0.1 | 0.3 | 0.1 | 0.1 |
11 | 1329 | 1312 ^ | Santolina epoxide * | 3.1 | |||||||||
12 | 1451 | 1400–1452 # | β-Thujone | 3.3 | 0.1 | ||||||||
13 | 1474 | 1453 ** | trans-Chrysanthenol | 2.0 | |||||||||
14 | 1532 | 1481–1537 # | Camphor | 51.3 | 41.7 | 41.1 | 26.6 | 23.0 | 37.7 | 32.5 | 35.9 | ||
15 | 1538 | 1533–1590 # | trans-Chrysanthenyl acetate | 8.1 | |||||||||
16 | 1553 | 1507–1564 # | Linalool | 3.8 | 2.5 | 0.1 | 0.2 | ||||||
17 | 1590 | 1549–1597 # | Bornyl acetate | 0.9 | 0.6 | 0.3 | 0.6 | 1.5 | 3.8 | 0.3 | 0.8 | ||
18 | 1611 | 1564–1630 # | Terpinen-4-ol | 2.7 | 2.9 | 2.4 | 3.8 | t | 3.3 | 6.9 | 2.0 | 2.3 | |
19 | 1687 | 1652–1690 # | Methyl chavicol | 42.9 | 38.8 | ||||||||
20 | 1719 | 1653–1728 # | Borneol | 2.4 | 3.3 | 9.6 | 8.1 | t | 6.6 | 14.6 | 2.9 | 2.3 | |
21 | 1737 | 1713–1748 # | (Z,E)-α-Farnesene | t | |||||||||
22 | 1748 | 1689–1748 # | Piperitone | 0.2 | 1.5 | 1.1 | |||||||
23 | 1758 | 1714–1763 # | (E,E)-α-Farnesene | 0.2 | 0.5 | ||||||||
24 | 1764 | 1751–1765 # | cis-Chrysanthenol | 0.5 | 0.8 | 1 | 0.5 | 3.9 | 0.5 | 0.2 | |||
25 | 1821 | 1807 *** | Fragranol | 3.0 | |||||||||
26 | 1827 | 1827 *** | Grandisol | 3.9 | |||||||||
27 | 1864 | 1813–1865 # | p-Cymen-8-ol | 0.2 | 0.1 | 0.1 | 2.3 | 0.9 | 0.4 | 0.3 | 0.1 | 0.1 | |
28 | 2030 | 1961–2033 # | Methyl eugenol | 26.1 | 26.4 | t | 0.1 | ||||||
29 | 2637 | 2608 ## | Xanthoxylin | 2.2 | 1.2 | ||||||||
Summary of the composition of Artemisia spp. essential oils | |||||||||||||
Compounds | ATLv | ATFl | ALLv | ALFl | ADLv | ADFl | AFLv | AFFl | ACLv | ACFl | |||
Monoterpene Hydrocarbons | 13.1 | 14.4 | 13.5 | 18.7 | 20.3 | 25.8 | 11.6 | 17.4 | 6.5 | 11.3 | |||
Oxygenated Monoterpenes | 84.5 | 79.8 | 82.5 | 77.4 | 4.0 | 1.9 | 79.6 | 79.8 | 84.8 | 81.0 | |||
Sesquiterpene Hydrocarbons | 2.0 | 0.2 | 0.7 | 1.7 | 2.4 | 0.6 | 0.2 | 0.1 | 0.3 | ||||
Oxygenated Sesquiterpenes | 0.8 | 1.6 | 1.1 | 1.2 | 1.7 | 1.1 | 2.5 | 0.6 | 0.1 | 0.4 | |||
Phenylpropanoids | 1.3 | 0.2 | 69.0 | 65.3 | 0.1 | 0.1 | |||||||
Others | t | t | 0.4 | 0.2 | 2.6 | 2.1 | 0.2 | 0.5 | t | 0.6 | |||
Total | 98.0 | 97.1 | 98.9 | 97.8 | 98.2 | 97.7 | 94.5 | 98.4 | 91.5 | 93.6 |
Legend: The data are presented as relative % for each component identified. RRIa, relative retention index calculated based on retention of n-alkanes. RRIb, relative retention indexes reported in the literature: # [28], @ [26]; ^ [29]; ** [30], *** [31,32], ## [33]. % was calculated from flame ionization detector data. Trace amounts (t) were present at <0.1%. * Santolina epoxide was tentatively identified using Wiley and MassFinder mass spectra libraries and published RRI. All other compounds were identified by comparison with co-injected standards. Abbreviations for the oil samples: ATLv, A. tridentata leaves; ATFl, A. tridentata flowers; ALLv, A. ludoviciana leaves; ALFl, A. ludoviciana flowers; ADLv, A. dracunculus leaves; ADFl, A. dracunculus flowers; AFLv, A. frigida leaves; AFFl, A. frigida flowers; ACLv, A. cana leaves; ACFl, A. cana flowers.