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. 2022 May 23;15(5):642. doi: 10.3390/ph15050642

Table 2.

Composition of essential oils (%) isolated from leaves and flowers of five Artemisia species.

No RRIa RRIb Compound ATLv ATFl ALLv ALFl ADLv ADFl AFLv AFFl ACLv ACFl
1 1032 1008–1039 # α-Pinene 2.1 1.8 2.5 3.9 0.1 0.1 2.2 3.3 0.8 2.0
2 1043 1011–1063 # Santolinatriene 0.7 1.7 3.5 2.2 2.4
3 1076 1043–1086 # Camphene 7.7 7.7 7.1 5.5 t t 4.0 6.0 1.6 4.1
4 1189 1179 @ Artemiseole 2.1 3.1 2.5 7.5 1.2
5 1213 1186–1231 # 1,8-Cineole 21.8 23.8 16.3 23.1 12.5 5.7 30.0 21.9
6 1218 1188–1233 # β-Phellandrene 1.3 2.2
7 1246 1211–1251 # (Z)-β-Ocimene 4.6 9.4
8 1266 1232–1267 # (E)-β-Ocimene 2.7 6.6 t
9 1280 1246–1291 # p-Cymene 1.2 1.2 0.7 0.7 0.5 0.2 3.2 2.1 0.9 0.7
10 1290 1260–1300 # Terpinolene t t 0.2 0.3 8.8 5.5 0.1 0.3 0.1 0.1
11 1329 1312 ^ Santolina epoxide * 3.1
12 1451 1400–1452 # β-Thujone 3.3 0.1
13 1474 1453 ** trans-Chrysanthenol 2.0
14 1532 1481–1537 # Camphor 51.3 41.7 41.1 26.6 23.0 37.7 32.5 35.9
15 1538 1533–1590 # trans-Chrysanthenyl acetate 8.1
16 1553 1507–1564 # Linalool 3.8 2.5 0.1 0.2
17 1590 1549–1597 # Bornyl acetate 0.9 0.6 0.3 0.6 1.5 3.8 0.3 0.8
18 1611 1564–1630 # Terpinen-4-ol 2.7 2.9 2.4 3.8 t 3.3 6.9 2.0 2.3
19 1687 1652–1690 # Methyl chavicol 42.9 38.8
20 1719 1653–1728 # Borneol 2.4 3.3 9.6 8.1 t 6.6 14.6 2.9 2.3
21 1737 1713–1748 # (Z,E)-α-Farnesene t
22 1748 1689–1748 # Piperitone 0.2 1.5 1.1
23 1758 1714–1763 # (E,E)-α-Farnesene 0.2 0.5
24 1764 1751–1765 # cis-Chrysanthenol 0.5 0.8 1 0.5 3.9 0.5 0.2
25 1821 1807 *** Fragranol 3.0
26 1827 1827 *** Grandisol 3.9
27 1864 1813–1865 # p-Cymen-8-ol 0.2 0.1 0.1 2.3 0.9 0.4 0.3 0.1 0.1
28 2030 1961–2033 # Methyl eugenol 26.1 26.4 t 0.1
29 2637 2608 ## Xanthoxylin 2.2 1.2
Summary of the composition of Artemisia spp. essential oils
Compounds ATLv ATFl ALLv ALFl ADLv ADFl AFLv AFFl ACLv ACFl
Monoterpene Hydrocarbons 13.1 14.4 13.5 18.7 20.3 25.8 11.6 17.4 6.5 11.3
Oxygenated Monoterpenes 84.5 79.8 82.5 77.4 4.0 1.9 79.6 79.8 84.8 81.0
Sesquiterpene Hydrocarbons 2.0 0.2 0.7 1.7 2.4 0.6 0.2 0.1 0.3
Oxygenated Sesquiterpenes 0.8 1.6 1.1 1.2 1.7 1.1 2.5 0.6 0.1 0.4
Phenylpropanoids 1.3 0.2 69.0 65.3 0.1 0.1
Others t t 0.4 0.2 2.6 2.1 0.2 0.5 t 0.6
Total 98.0 97.1 98.9 97.8 98.2 97.7 94.5 98.4 91.5 93.6

Legend: The data are presented as relative % for each component identified. RRIa, relative retention index calculated based on retention of n-alkanes. RRIb, relative retention indexes reported in the literature: # [28], @ [26]; ^ [29]; ** [30], *** [31,32], ## [33]. % was calculated from flame ionization detector data. Trace amounts (t) were present at <0.1%. * Santolina epoxide was tentatively identified using Wiley and MassFinder mass spectra libraries and published RRI. All other compounds were identified by comparison with co-injected standards. Abbreviations for the oil samples: ATLv, A. tridentata leaves; ATFl, A. tridentata flowers; ALLv, A. ludoviciana leaves; ALFl, A. ludoviciana flowers; ADLv, A. dracunculus leaves; ADFl, A. dracunculus flowers; AFLv, A. frigida leaves; AFFl, A. frigida flowers; ACLv, A. cana leaves; ACFl, A. cana flowers.