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. 2022 May 30;13:3005. doi: 10.1038/s41467-022-30560-9

Fig. 5. Evolution process of DOTP and thermodynamic feasibility analysis.

Fig. 5

a Proposed elementary reaction pathways of the oxidative coupling and polymerization of PhOH on the catalyst surface in the DOTP. b Competitive inhibition of acetonitrile on PhOH removal. c Removal processes of PhOH in H2O and D2O. d Corresponding kinetic curves of c. The KIE value was calculated to be KH/KD ~1.4, which is in the range of secondary kinetic isotope effects. e Thermodynamic potential energy curves during the reaction in DOTP. f Thermodynamic potential energy curves of the reductive and oxidative activation processes of PMS on the Co3O4 surface in the AOP. PR polymerization reaction, CR coupling reaction.