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Diffusion coefficient (average±SD) of chloride anion (Cl−) in reference and saturated NaCl, KCl, RbCl and CsCl solutions, obtained through 35Cl‐based PFG NMR measurements (A, B). The most significant drop in diffusion coefficient of Cl− ion was observed in saturated NaCl solution. Severe 35Cl relaxation losses precluded diffusion measurement in saturated LiCl solution (B). Dilute alkali chloride solutions were used as reference.
