Skip to main content
. 2022 May 20;38(21):6700–6710. doi: 10.1021/acs.langmuir.2c00633

Figure 9.

Figure 9

(a) Schematic of the mass flows into and out of the precipitate structure. Injection feeds cobalt chloride through the nozzle at the center; silicate ions are driven from the outer fluid and consumed in the precipitation reaction to form a membrane; the concentration gradient established across the membrane drives water into the structure through osmosis. (b) Density changes occur in the system: the reaction forms a precipitate product with a higher density than the liquid reactants, and the overall structure thus consists of the injected inner liquid and the precipitate product, with an effective density ρeff. The consumption of silicate ions in the reaction also leads to a decrease in the density of the outer fluid, which is assumed to be negligible here.