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. 2022 May 20;9:908175. doi: 10.3389/fnut.2022.908175

Table 4.

The IR wavenumbers of functional groups in polysaccharides.

Functional group Vibration mode Wavenumbers/cm−1
-OH O-H, ν (stretching vibration) 3,700–3,100
O-H, δ (scissoring vibration) 1,075–1,010; 1,120–1,105
-COOH C=O 1,740–1,680
C-O 1,440–1,395
O-H 1,320–1,210
-O-COR C=O 1,749–1,725
C-O 1,245
-NH2 N-H, ν 3,450–3,380
N-H, δ 1,650–1,500
=NH N-H, ν 3,460–3,420
-NH+ 3 N=H 3,350–3,150
N-H 1,650–1,550
-C-O-C C-O (fatty ether) 1,150–1,060
C-O (cyclic ether) 1,150–1,080
-CH2 C-H, ν 2,926–2,853
C-H, δ 1,465
-CH3 C-H, ν 2,962; 2,872
-C=O
-CHO
C=O 1,780–1,540
C=O 1,740, 1,650
α-D-Glcp C-H 855–833
β-D-Glcp 905–876
α-D-Galp 839–810
β-D-Galp 914–886
α-D-Manp 843–818
β-D-Manp 898–888
α-D-Xylp 760–740
β-D-Arbp 855–830