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. 2022 Jun 6;12(26):16396–16411. doi: 10.1039/d2ra00673a

Example of hybrid photosystems.

System Biological substance Light absorber Reaction Production rates/yields/activity Comments Reference
Inorganic Magnesium–aluminium–LDH/carbon nitride CO2 to CH4 3.7 μmol in 24 hours 30
NaNbO3 nanowire CO2 to CH4 653 ppm h−1 g−1 31
NaNbO3 bulk 32 ppm h−1 g−1
Cobalt-ZIF-CdS CO2 to CO + H2 124.4 μmol in 3 hours TEOA = SED, bipyridine = e transfer assistant, 82% CO selectivity 23
Lanthanum/rhodium-doped strontium titanium(iii) oxide photosheet CO2 to formate 0.08% solar to formate conversion efficiency 97% formate selectivity 142
Enzymatic Carbon monoxide dehydrogenase I Anatase/rutile TiO2–RuP CO2 to CO 0.14 s−1 2-(N-Morpholino)ethanesulfonic acid = SED 45
Formate dehydrogenase tetrakis(4-methylpyridyl)porphyrin CO2 to HCOOH 62 μM in 3 hours TEOA = SED 42
MV2+ = e mediator
Microbial E. coli Silver indium sulfide/indium sulfide H+ to H2 1660 μmol in 3 hours Cysteine = SED 68
M. thermoacetica Gold nanocluster CO2 to acetate 6.01 mmol g−1 over 7 days Cysteine = SED 67
S. ovata Silicon nanowires CO2 to acetate 0.3 g L−1 over 7 days 104
R. palustris Graphitic carbon nitride Fructose to PHB 6.73 g L−1 after 96 hours TEOA = SED 69
R. eutropha CdS nanorods CO2 to PHB 28 mg over 48 hours 10% lactic acid = SED 70
Graphitic carbon nitride catalyse CO2 to PHB 41.02 mg L−1 after 48 hours 73
Core–shell QDs PHB 100 mg g−1 d−1 l-Ascorbic acid or HEPES = SED 71
2,3-Butanediol 10 mg g−1 d−1
Ethylene 1 mg g−1 d−1
Isopropanol 2 mg g−1 d−1
R. capsulata Bi2O3 H+ to H2 ∼0.26 mL h−1 MV2+ = e mediator 80
EDTA = SED
M. barkeri n+/p-Si/NiMo CO2 to CH4 17.6 mL over 72 hours H2 = e donor 107
CdS CO2 to CH4 0.19 μmol h−1/13.70 μmol Cysteine = SED 64