Inorganic |
— |
Magnesium–aluminium–LDH/carbon nitride |
CO2 to CH4
|
3.7 μmol in 24 hours |
— |
30
|
— |
NaNbO3 nanowire |
CO2 to CH4
|
653 ppm h−1 g−1
|
— |
31
|
NaNbO3 bulk |
32 ppm h−1 g−1
|
— |
— |
Cobalt-ZIF-CdS |
CO2 to CO + H2
|
124.4 μmol in 3 hours |
TEOA = SED, bipyridine = e− transfer assistant, 82% CO selectivity |
23
|
— |
Lanthanum/rhodium-doped strontium titanium(iii) oxide photosheet |
CO2 to formate |
0.08% solar to formate conversion efficiency |
97% formate selectivity |
142
|
Enzymatic |
Carbon monoxide dehydrogenase I |
Anatase/rutile TiO2–RuP |
CO2 to CO |
0.14 s−1
|
2-(N-Morpholino)ethanesulfonic acid = SED |
45
|
Formate dehydrogenase |
tetrakis(4-methylpyridyl)porphyrin |
CO2 to HCOOH |
62 μM in 3 hours |
TEOA = SED |
42
|
MV2+ = e− mediator |
Microbial |
E. coli
|
Silver indium sulfide/indium sulfide |
H+ to H2
|
1660 μmol in 3 hours |
Cysteine = SED |
68
|
M. thermoacetica
|
Gold nanocluster |
CO2 to acetate |
6.01 mmol g−1 over 7 days |
Cysteine = SED |
67
|
S. ovata
|
Silicon nanowires |
CO2 to acetate |
0.3 g L−1 over 7 days |
— |
104
|
R. palustris
|
Graphitic carbon nitride |
Fructose to PHB |
6.73 g L−1 after 96 hours |
TEOA = SED |
69
|
R. eutropha
|
CdS nanorods |
CO2 to PHB |
28 mg over 48 hours |
10% lactic acid = SED |
70
|
Graphitic carbon nitride catalyse |
CO2 to PHB |
41.02 mg L−1 after 48 hours |
— |
73
|
Core–shell QDs |
PHB |
100 mg g−1 d−1
|
l-Ascorbic acid or HEPES = SED |
71
|
2,3-Butanediol |
10 mg g−1 d−1
|
Ethylene |
1 mg g−1 d−1
|
Isopropanol |
2 mg g−1 d−1
|
R. capsulata
|
Bi2O3
|
H+ to H2
|
∼0.26 mL h−1
|
MV2+ = e− mediator |
80
|
EDTA = SED |
|
M. barkeri
|
n+/p-Si/NiMo |
CO2 to CH4
|
17.6 mL over 72 hours |
H2 = e− donor |
107
|
CdS |
CO2 to CH4
|
0.19 μmol h−1/13.70 μmol |
Cysteine = SED |
64
|