. 2022 May 24;87(11):7456–7463. doi: 10.1021/acs.joc.2c00955

Table 1. Second-Order Rate Constants (k_H) for Reaction of the Cumyloxyl Radical (CumO^•) With Lactams and Other Nitrogen-Containing Heterocycles^a.

Measured in argon-saturated acetonitrile solution at T = 25 °C employing 355 nm LFP: [dicumyl peroxide] = 1.0 M. Average of at least two independent experiments.

Measured in DMSO solution.

Table 1. Second-Order Rate Constants (kH) for Reaction of the Cumyloxyl Radical (CumO•) With Lactams and Other Nitrogen-Containing Heterocyclesa.

Table 1. Second-Order Rate Constants (k_H) for Reaction of the Cumyloxyl Radical (CumO^•) With Lactams and Other Nitrogen-Containing Heterocycles^a.